Portuguese winger Simao said Portugal could beat five-time champions Brazil but admitted he wanted to avoid Spain in the next phase.
The Portuguese, semi-finalists at the 2006 World Cup, are grouped with Brazil, Cote d'Ivoire and the DPR Korea in Group G, regarded as the "Group of Death".
"Portugal have some of the best players in Europe with a lot of ambition and it's a very united and strong team," Simao told reporters at Portugal's training base outside Johannesburg.
"It's always important to start the World Cup in the best way with a win. We don't want to face Brazil in the third game needing a win but if we need to win, why not? Because we have beaten them several times before."
But he said Portugal would try to avoid Spain in the last 16, which would happen if Spain topped Group H and Portugal finished as runners-up in their group.
"It will be difficult if Portugal face Spain in the last 16 because they are the European champions," the 30-year-old said. Spain are hot favourites to top Group H.
2017届高考英语一轮模块训练:模块6 Unit 2 What is happiness to you(译林版)
2017届高考英语一轮配套学以致用训练:8-2 《Cloning》
2017届高考英语一轮配套学以致用训练:3-4 《Astronomy:the science of the stars》
2017届高考英语一轮配套学以致用训练:7-3 《Under the sea》
2017届高考英语一轮配套学以致用训练:7-4 《Sharing》
2017届高考英语一轮配套学以致用训练:4-1 《Women of achievement》
2017届高考英语一轮模块训练:模块7 Unit 1 Living with technology(译林版)
2017届高考英语一轮配套学以致用训练:1-3 《Travel journal》
2017届高考英语一轮模块训练:模块6 Unit 3 Understanding each other(译林版)
2017届高考英语一轮配套学以致用训练:6-3 《A healthy life》
2017届高考英语一轮模块训练:模块7 Unit 2 Fit for life(译林版)
2017届高考英语一轮配套学以致用训练:4-5 《Theme parks》
2017届高考英语一轮配套学以致用训练:1-5 《Nelson Mandela — a modern hero》
2017届高考英语一轮配套学以致用训练:4-4 《Body language》
2017届高考英语一轮配套学以致用训练:2-1 《Cultural relics》
2017届高考英语一轮配套学以致用训练:5-1 《Great scientists》
2017届高考英语一轮配套学以致用训练:5-3 《Life in the future》
2017届高考英语一轮配套学以致用训练:1-4 《Earthquakes》
2017届高考英语一轮配套学以致用训练:8-3 《Inventors and inventions》
2017届高考英语一轮配套学以致用训练:6-4 《Global warming》
2017届高考英语一轮配套学以致用训练:2-5 《Music》
2017届高考英语一轮配套学以致用训练:6-5 《The power of nature》
2017届高考英语一轮配套学以致用训练:3-2 《Healthy eating》
2017届高考英语一轮配套学以致用训练:8-5 《Meeting your ancestors》
2017届高考英语一轮配套学以致用训练:5-2 《The United Kingdom》
2017届高考英语一轮配套学以致用训练:4-3 《A taste of English humour》
2017届高考英语一轮配套学以致用训练:7-5 《Travelling abroad》
2017届高考英语一轮配套学以致用训练:2-3 《Computers》
2017届高考英语一轮配套学以致用训练:6-1 《Art》
2017届高考英语一轮配套学以致用训练:1-2 《English around the world》
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